Ozone Layer Essay Words __HOT__
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The ozone layer sits in the stratosphere between 15 km and 30 km above the earth. It absorbs most of the sun's ultraviolet radiation (UV-B), limiting the amount of this radiation that reaches the surface of the Earth. Because this radiation causes skin cancer and cataracts, the ozone layer plays an important role in protecting human health. It also prevents radiation damage to plants, animals, and materials.
In the 1970s, scientists noticed that the ozone layer was thinning. Researchers found evidence that linked the depletion of the ozone layer to the presence of chlorofluorocarbons (CFCs) and other halogen-source gases in the stratosphere. Ozone-depleting substances (ODS) are synthetic chemicals, which were used around the world in a wide range of industrial and consumer applications. The main uses of these substances were in refrigeration and air conditioning equipment and in fire extinguishers. Other important uses included aerosol propellants, solvents and blowing agents for insulation foams.
To halt the depletion of the ozone layer, countries around the world agreed to stop using ozone-depleting substances. This agreement was formalised in the Vienna Convention for the Protection of the Ozone Layer in 1985 and the Montreal Protocol on Substances that Deplete the Ozone Layer in 1987. In 2009, the Vienna Convention and the Montreal Protocol became the first treaties in the history of the United Nations to achieve universal ratification. Substances covered by the protocol are referred to as 'controlled substances'. The main substances include chlorofluorocarbons (CFCs), hydrochlorofluorocarbons (HCFCs), halons, carbon tetrachloride, methyl chloroform and methyl bromide. The damage to the ozone layer caused by each of these substances is expressed as their ozone depletion potential (ODP).
These international agreements helped to greatly reduce the worldwide use of ozone-depleting substances in Europe and around the World (Figure 1). Scientific monitoring shows signs that the ozone layer is starting to recover. Full recovery is not expected to occur before the middle of the 21st century.
The reduction in ozone-depleting substances has also had a beneficial side-effect. Ozone-depleting substances are also very potent greenhouse gases, contributing to the phenomenon as other substances widely known to have a greenhouse effect like carbon dioxide (CO2), methane (CH4) and nitrous oxide (N2O). Therefore, by reducing emissions of ozone-depleting substances, the Montreal Protocol has protected both the ozone layer and the climate at the same time.
The reduction of ODS emissions is not a uniformly positive story. In fact it has indirectly led to new problems. Fluorinated gases (F-gases) have been introduced as substitutes for ODS in many sectors such as refrigeration and air conditioning applications. F-gases include hydrofluorocarbons (HFCs), perfluorocarbons (PFCs) and sulphur hexafluoride (SF6). These gases do not deplete the ozone layer, but they are greenhouse gases. This means that these new gases also contribute to climate change. And to make matters worse, these F-gases often have a far larger impact on the climate than 'traditional' greenhouse gases such as carbon dioxide (CO2). For example, some F-gases have a greenhouse effect that is up to 23 000 times more powerful than the same amount of carbon dioxide. Fortunately, the emissions of F-gases are far smaller than those of CO2, but the use of F-gases and their presence in the atmosphere have increased since the 1990s. As a result, the significant contribution of the Montreal Protocol to fighting climate change is in danger of being wiped out by the growing importance of F-gas emissions.
Because F-gases contribute to climate change, businesses are now looking to replace them with other substances. Alternatives that do not damage the ozone layer or contribute to climate change have become available over recent years in a variety of applications such as refrigeration, air conditioning, foam blowing and aerosols. Many of these alternatives lead also to higher energy efficiency which is important as the indirect emissions from energy use during the lifespan of a product are often considerably higher than direct emissions of F-gases.
The phaseout of controlled uses of ozone depleting substances and the related reductions have not only helped protect the ozone layer for this and future generations, but have also contributed significantly to global efforts to address climate change; furthermore, it has protected human health and ecosystems by limiting the harmful ultraviolet radiation from reaching the Earth.
A number of commonly used chemicals have been found to be extremely damaging to the ozone layer. Halocarbons are chemicals in which one or more carbon atoms are linked to one or more halogen atoms (fluorine, chlorine, bromine or iodine). Halocarbons containing bromine usually have much higher ozone-depleting potential (ODP) than those containing chlorine. The man-made chemicals that have provided most of the chlorine and bromine for ozone depletion are methyl bromide, methyl chloroform, carbon tetrachloride and families of chemicals known as halons, chlorofluorocarbons (CFCs) and hydrochlorofluorocarbons (HCFCs).
The scientific confirmation of the depletion of the ozone layer prompted the international community to establish a mechanism for cooperation to take action to protect the ozone layer. This was formalized in the Vienna Convention for the Protection of the Ozone Layer, which was adopted and signed by 28 countries, on 22 March 1985. In September 1987, this led to the drafting of The Montreal Protocol on Substances that Deplete the Ozone Layer.
The principal aim of the Montreal Protocol is to protect the ozone layer by taking measures to control total global production and consumption of substances that deplete it, with the ultimate objective of their elimination on the basis of developments in scientific knowledge and technological information. It is structured around several groups of ozone-depleting substances. The groups of chemicals are classified according to the chemical family and are listed in annexes to the Montreal Protocol text. The Protocol requires the control of nearly 100 chemicals, in several categories. For each group or annex of chemicals, the Treaty sets out a timetable for the phase-out of production and consumption of those substances, with the aim of eventually eliminating them completely.
The ozone layer or ozone shield is a region of Earth's stratosphere that absorbs most of the Sun's ultraviolet radiation. It contains a high concentration of ozone (O3) in relation to other parts of the atmosphere, although still small in relation to other gases in the stratosphere. The ozone layer contains less than 10 parts per million of ozone, while the average ozone concentration in Earth's atmosphere as a whole is about 0.3 parts per million. The ozone layer is mainly found in the lower portion of the stratosphere, from approximately 15 to 35 kilometers (9 to 22 mi) above Earth, although its thickness varies seasonally and geographically.[1]
The ozone layer absorbs 97 to 99 percent of the Sun's medium-frequency ultraviolet light (from about 200 nm to 315 nm wavelength), which otherwise would potentially damage exposed life forms near the surface.[3]
In 1976, atmospheric research revealed that the ozone layer was being depleted by chemicals released by industry, mainly chlorofluorocarbons (CFCs). Concerns that increased UV radiation due to ozone depletion threatened life on Earth, including increased skin cancer in humans and other ecological problems,[4] led to bans on the chemicals, and the latest evidence is that ozone depletion has slowed or stopped. The United Nations General Assembly has designated September 16 as the International Day for the Preservation of the Ozone Layer.
The photochemical mechanisms that give rise to the ozone layer were discovered by the British physicist Sydney Chapman in 1930. Ozone in the Earth's stratosphere is created by ultraviolet light striking ordinary oxygen molecules containing two oxygen atoms (O2), splitting them into individual oxygen atoms (atomic oxygen); the atomic oxygen then combines with unbroken O2 to create ozone, O3. The ozone molecule is unstable (although, in the stratosphere, long-lived) and when ultraviolet light hits ozone it splits into a molecule of O2 and an individual atom of oxygen, a continuing process called the ozone-oxygen cycle. Chemically, this can be described as:
UV-C, which is very harmful to all living things, is entirely screened out by a combination of dioxygen (< 200 nm) and ozone (> about 200 nm) by around 35 kilometres (115,000 ft) altitude. UV-B radiation can be harmful to the skin and is the main cause of sunburn; excessive exposure can also cause cataracts, immune system suppression, and genetic damage, resulting in problems such as skin cancer. The ozone layer (which absorbs from about 200 nm to 310 nm with a maximal absorption at about 250 nm)[7] is very effective at screening out UV-B; for radiation with a wavelength of 290 nm, the intensity at the top of the atmosphere is 350 million times stronger than at the Earth's surface. Nevertheless, some UV-B, particularly at its longest wavelengths, reaches the surface, and is important for the skin's production of vitamin D in mammals.
The thickness of the ozone layer varies worldwide and is generally thinner near the equator and thicker near the poles.[9] Thickness refers to how much ozone is in a column over a given area and varies from season to season. The reasons for these variations are due to atmospheric circulation patterns and solar intensity.[10]
The ozone layer can be depleted by free radical catalysts, including nitric oxide (NO), nitrous oxide (N2O), hydroxyl (OH), atomic chlorine (Cl), and atomic bromine (Br). While there are natural sources for all of these species, the concentrations of chlorine and bromine increased markedly in recent decades because of the release of large quantities of man-made organohalogen compounds, especially chlorofluorocarbons (CFCs) and bromofluorocarbons.[12] These highly stable compounds are capable of surviving the rise to the stratosphere, where Cl and Br radicals are liberated by the action of ultraviolet light. Each radical is then free to initiate and catalyze a chain reaction capable of breaking down over 100,000 ozone molecules. By 2009, nitrous oxide was the largest ozone-depleting substance (ODS) emitted through human activities.[13] 2b1af7f3a8